Spectral properties of molecular oligomers. A non-Markovian quantum state diffusion approach
نویسندگان
چکیده
Abstract. Absorption spectra of small molecular aggregates (oligomers) are considered. The dipole-dipole interaction between the monomers leads to shifts of the oligomer spectra with respect to the monomer absorption. The line-shapes of monomer as well as oligomer absorption depend strongly on the coupling to vibrational modes. Using a recently developed approach [Roden et. al, PRL 103, 058301] we investigate the length dependence of spectra of one-dimensional aggregates for various values of the interaction strength between the monomers. It is demonstrated, that the present approach is well suited to describe the occurrence of the Jand H-bands.
منابع مشابه
Synchronization in Periodically Driven and Coupled Stochastic Systems--A Discrete State Approach
We investigate the behavior of stochastic bistable and excitable dynamics based on a discrete state modeling. In addition to the well known Markovian two state model for bistable dynamics we introduce a non Markovian three state model for excitable systems. Its relative simplicity compared to stochastic models of excitable dynamics with continuous phase space allows to obtain analytical results...
متن کاملQuantum dynamics with non-Markovian fluctuating parameters.
A stochastic approach to the quantum dynamics randomly modulated in time by a discrete state non-Markovian noise, which possesses an arbitrary nonexponential distribution of the residence times, is developed. The formally exact expression for the Laplace-transformed quantum propagator averaged over the stationary realizations of such N -state non-Markovian noise is obtained. The theory possesse...
متن کاملSpectral Separation of Quantum Dots within Tissue Equivalent Phantom Using Linear Unmixing Methods in Multispectral Fluorescence Reflectance Imaging
Introduction Non-invasive Fluorescent Reflectance Imaging (FRI) is used for accessing physiological and molecular processes in biological media. The aim of this article is to separate the overlapping emission spectra of quantum dots within tissue-equivalent phantom using SVD, Jacobi SVD, and NMF methods in the FRI mode. Materials and Methods In this article, a tissue-like phantom and an optical...
متن کاملNon-Markovian quantum state diffusion: Perturbation approach
We present a perturbation theory for non-Markovian quantum state diffusion (QSD), the theory of diffusive quantum trajectories for open systems in a bosonic environment [Physical Review A 58, 1699, (1998)]. We establish a systematic expansion in the ratio between the environmental correlation time and the typical system time scale. The leading order recovers the Markov theory, so here we concen...
متن کاملLinear quantum state diffusion for non-Markovian open quantum systems
We demonstrate the relevance of complex Gaussian stochastic processes to the stochastic state vector description of non-Markovian open quantum systems. These processes express the general Feynman-Vernon path integral propagator for open quantum systems as the classical ensemble average over stochastic pure state propagators in a natural way. They are the coloured generalization of complex Wiene...
متن کامل